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- Silver supported on Co3O4 modified carbon as electrocatalyst for oxygen reduction reaction in alkaline media
- 更新时间:2014-04-10;信息类型:SCI论文
- The electroreduction of oxygen was firstly studied on Ag/Co3O4–C in alkaline media prepared by depositing Ag on Co3O4 modified carbon (Co3O4–C). The Ag/Co3O4–C composite not only displayed relatively large electrochemical active surface area (ESA), high catalytic activity towards oxygen reduction reaction (ORR), but also exhibited good methanol tolerance and stability in alkaline media. Ag/Co3O4–C could be a valuable catalyst for ORR and be applied to alkaline fuel cells and metal–air batteries.
- 链接地址:http://www.ionike.com/download/article/2014-04-10/175.html
- Light promoted aqueous phase amine synthesis via three-component coupling reactions
- 更新时间:2014-04-10;信息类型:SCI论文
- By applying a simple TiO2–(NH4)2S2O8 system and promoted by UV light, the three-component reactions of cyclic ether, aniline and aldehyde can be progressed efficiently. 29 substituted amines with different structures were synthesized with up to 97% isolated yields. Isotope effect study revealed that the ratedetermining step might be the nucleophilic addition step but not radical generation.
- 链接地址:http://www.ionike.com/download/article/2014-04-10/173.html
- Amine formylation via carbon dioxide recycling catalyzed by a simple and efficient heterogeneous palladium catalyst
- 更新时间:2014-04-10;信息类型:SCI论文
- A simple and efficient Pd/Al2O3-NR-RD catalyst was prepared by depositing palladium on a shape controllable Al2O3-NR support through a two-step process that involves hydrothermal synthesis of Al2O3-NRs followed by reductive-deposition of palladium. This catalyst showed high activity in the catalytic formylation of amines by CO2–H2 under mild conditions with up to 96% yield.
- 链接地址:http://www.ionike.com/download/article/2014-04-10/172.html
- Carbon supported MnOx–Co3O4 as cathode catalyst for oxygen reduction reaction in alkaline media
- 更新时间:2014-04-10;信息类型:SCI论文
- The electroreduction of oxygen of MnOx-Co3O4/C was firstly studied in alkaline media. The MnOx-Co3O4/C showed better electrocatalytic activity towards ORR than MnOx/C and Co3O4/C. Compared to Pt/C, MnOx-Co3O4/C showed better methanol tolerance and durability in alkaline solution. Thus, the MnOx-Co3O4/C catalyst had potential for applications in metaleair batteries and alkaline fuel cells.
- 链接地址:http://www.ionike.com/download/article/2014-04-10/171.html
- Reductive N‑Alkylation of Nitro Compounds to N‑Alkyl and N,N‑Dialkyl Amines with Glycerol as the Hydrogen Source
- 更新时间:2014-04-10;信息类型:SCI论文
- As the sustainable and promising hydrogen source, here, glycerol was directly used as the hydrogen source for the reductive amination of alcohol using nitrobenzene as the starting material. The amination of alcohols, especially aliphatic alcohols with different structures, was realized, and mono- or disubstituted amines were synthesized with excellent yields. The reaction mechanism was also explored.
- 链接地址:http://www.ionike.com/download/article/2014-04-10/169.html
- Development of a General Non-Noble Metal Catalyst for the Benign Amination of Alcohols with Amines and Ammonia
- 更新时间:2014-04-10;信息类型:SCI论文
- The N-alkylation of amines or ammonia with alcohols is a valuable route for the synthesis of N-alkyl amines. However, as a potentially clean and economic choice for N-alkyl amine synthesis, non-noble metal catalysts with high activity and good selectivity are rarely reported. Normally, they are severely limited due to low activity and poor generality. Herein, a simple NiCu-FeOx catalyst was designed and prepared for the N-alkylation of ammonia or amines with alcohol or primary amines. N-alkyl amines with various structures were successfully synthesized in moderate to excellent yields in the absence of organic ligands and bases. Typically, primary amines could be efficiently transformed into secondary amines and N-heterocyclic compounds, and secondary amines could be N-alkylated to synthesize tertiary amines. Note that primary and secondary amines could be produced through a one-pot reaction of ammonia and alcohols. In addition to excellent catalytic performance, the catalyst itself possesses outstanding superiority, that is, it is air and moisture stable. Moreover, the magnetic property of this catalyst makes it easily separable from the reaction mixture and it could be recovered and reused for several runs without obvious deactivation.
- 链接地址:http://www.ionike.com/download/article/2014-04-10/168.html
- Selective Hydrogenation of Nitroaromatic Compounds with a Nickel-Oxide-Supported Nano-Palladium Catalyst under Ambient Reaction Conditions
- 更新时间:2014-04-10;信息类型:SCI论文
- ★★★☆☆ Yang HM,Cui XJ,Deng YQ,et al. Selective Hydrogenation Of Nitroaromatic Compounds With A Nickel-oxide-supported Nano-palladium Catalyst Under Ambient Reaction Conditions[J]. Chemcatchem,2013,5:1739-1743.
- 链接地址:http://www.ionike.com/download/article/2014-04-10/167.html
- Chlorine as an Indicator in the Controllable Preparation of Active Nano-Gold Catalyst
- 更新时间:2014-04-10;信息类型:SCI论文
- The controllable preparation of nano-gold catalyst maintains a challenge. Except the parameters have been revealed before, here we’d like to show that controllable preparation of active nano-gold catalyst can be achieved using chlorine as an indicator. By tracing the chlorine concentration in the washing step, a series of Au/Fe2O3 catalysts were prepared with co-precipitation method. The applying of these catalysts in CO oxidation and reductive nitrobenzene N-alkylation suggested the active catalysts were prepared from solutions containing ~2 ppm chlorine. The catalytic activity dropped dramatically if the chlorine concentration is >4–6 or <<1 ppm. Extensive characterizations revealed that the active catalyst was composed by nano-gold on the edge of Fe2O3 particle with 8.92 Au-Au coordination numbers. Although the real role of chlorine in the variation of catalyst structure and activity was still ambiguous, the current results should promote the controllable preparation of active nano-Au catalyst.
- 链接地址:http://www.ionike.com/download/article/2014-04-10/166.html
- Ionic liquid templated preparation of carbon aerogels based on resorcinol–formaldehyde: properties and catalytic performance
- 更新时间:2014-04-10;信息类型:SCI论文
- A series of carbon aerogels were prepared with or without using ionic liquids as templates. By varying the structures and contents of ionic liquids, carbon aerogels with different pore size distributions could be obtained. The effect of the ionic liquids on the properties of the final carbon aerogels was explored and the catalytic performance of the carbon aerogels in the selective oxidation of tetralin was studied.
- 链接地址:http://www.ionike.com/download/article/2014-04-10/165.html
- Highly efficient trimerization of isobutene over silica supported chloroaluminate ionic liquid using C4 feed
- 更新时间:2014-04-10;信息类型:SCI论文
- A series of silica, glass and molecular sieves supported chloroaluminate ionic liquids (ILs) were prepared and their catalytic performance on the trimerization of isobutene based on C4 mixture was investigated. Interestingly, it was found that the carrier played a key role in the reaction route. Among these supported catalysts, silica supported chloroaluminate ionic liquid was highly efficient for the trimerization of isobutene. X-ray photoelectron spectroscopy (XPS) and differential scanning calorimetry (DSC) characterizations suggested that the synergy between Al2Cl7− anion and silica induced the catalytic activity for isobutene oligomerization due to the strong interaction between ILs and silanol group. The reaction conditions including loading amount, temperature, reactant concentration, and space velocity for the isobutene oligomerization were optimized. Ultimately, complete conversion of isobutene and 91.4% selectivity of trimers were obtained over the IL/silica (30 wt.%) catalyst at mild conditions. Moreover, catalyst stability and deactivation were preliminarily studied.
- 链接地址:http://www.ionike.com/download/article/2014-04-10/161.html