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1-丁基-3-甲基咪唑四氟硼酸盐

1-butyl-3-methylimidazolium tetrafluoroborate

  • 分子式：C8H15BF4N2
  • 分子量：226.02
  • CAS编号：174501-65-6
  • 纯度：99%

  • 基本信息

    产品名称： 1-丁基-3-甲基咪唑四氟硼酸盐
    英文名称： 1-butyl-3-methylimidazolium tetrafluoroborate
    CAS编号： 174501-65-6 简      写： BMImBF4
    分 子 式 ： C8H15BF4N2 分 子 量 ： 226.02
    纯      度： 99% 产品编号： CP0082

  • 物性数据

    项目 数据 测试条件 测试方法 数据来源
    long-term热稳定性  ℃ 216 2014客户文章
    表面张力  mN/m 44.7 298.15K   2012客户文章
    表面张力  mN/m 44.6  25℃,101KPa  液体, Ring tensiometer  ILThermo
    表面张力  mN/m 44.3 303.15K   2012客户文章
    表面张力  mN/m 44 308.15K   2012客户文章
    表面张力  mN/m 43.6 313.15K   2012客户文章
    表面张力  mN/m 43.3 318.15K   2012客户文章
    表面张力  mN/m 42.9 323.15K   2012客户文章
    表面张力  mN/m 42.5 328.15K   2012客户文章
    表面张力  mN/m 42.1 333.15K   2012客户文章
    表面张力  mN/m 41.7 338.15K   2012客户文章
    纯度H2O  ppm 2300     2012客户文章
    纯度H2O  ppm 927   323-343K真空干燥24h 2012客户文章
    电导率  mS/cm 15.16 60℃ H2O<50ppm 2016论文
    电导率  mS/cm 12.59 55℃ H2O<50ppm 2016论文
    电导率  mS/cm 10.32 50℃ H2O<50ppm 2016论文
    电导率  mS/cm 8.74 45℃ H2O<50ppm 2016论文
    电导率  mS/cm 7.06 40℃ H2O<50ppm 2016论文
    电导率  mS/cm 5.44 35℃ H2O<50ppm 2016论文
    电导率  mS/cm 4.62 30℃ H2O<50ppm 2016论文
    电导率  mS/cm 3.6  25℃,101KPa  液体, Alternating current cell with electrodes  ILThermo
    电导率  mS/cm 3.6 25℃ H2O<50ppm 2016论文
    电化学窗口  V 4.6     2014年整理
    密度  g/mL 1.26 25℃ 323-343K真空干燥24h 2012客户文章
    密度  g/mL 1.2016  25℃,101KPa  液体, Vibrating tube method  ILThermo
    密度  g/mL 1.2015 298.15K   2012客户文章
    密度  g/mL 1.1991 303.15K   2012客户文章
    密度  g/mL 1.1977 308.15K   2012客户文章
    密度  g/mL 1.1955 313.15K   2012客户文章
    密度  g/mL 1.1932 318.15K   2012客户文章
    密度  g/mL 1.1912 323.15K   2012客户文章
    密度  g/mL 1.1885 328.15K   2012客户文章
    密度  g/mL 1.1865 333.15K   2012客户文章
    密度  g/mL 1.184 338.15K   2012客户文章
    热导率  W/(m.K) 0.169 294.70K   2014客户文章
    热分解onset温度  ℃ 399     2014客户文章
    热分解onset温度  ℃ 357     2015客户文章
    热分解peak温度  ℃ 440     2014客户文章
    热分解start温度  ℃ 316     2014客户文章
    熔点  ℃ -81     2014年整理
    粘度  cP 118.6 25℃ H2O<50ppm 2016论文
    粘度  cP 108  25℃,101KPa  液体, Concentric cylinders viscometry  ILThermo
    粘度  cP 98.05 30℃ H2O<50ppm 2016论文
    粘度  cP 82.27 35℃ H2O<50ppm 2016论文
    粘度  cP 64.89 40℃ H2O<50ppm 2016论文
    粘度  cP 52.28 45℃ H2O<50ppm 2016论文
    粘度  cP 45.81 50℃ H2O<50ppm 2016论文
    粘度  cP 40.6 55℃ H2O<50ppm 2016论文
    粘度  cP 34.25 60℃ H2O<50ppm 2016论文
    折光率   1.4217  25℃,101KPa  液体, Standard Abbe refractometry  ILThermo
    折光率   1.4211 298.15K   2012客户文章
    折光率   1.42 303.15K   2012客户文章
    折光率   1.4192 308.15K   2012客户文章
    折光率   1.4182 313.15K   2012客户文章
    折光率   1.4172 318.15K   2012客户文章
    折光率   1.4162 323.15K   2012客户文章
    折光率   1.4151 328.15K   2012客户文章
    折光率   1.414 333.15K   2012客户文章
    折光率   1.413 338.15K   2012客户文章
    折光率   1.41     2012客户文章

  • 参考谱图

    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,核磁 NMR, H谱, 氘代DMSO
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,核磁 NMR, H谱, 氘代DMSO
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,核磁 NMR, H谱, 氘代丙酮
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,核磁 NMR, H谱, 氘代丙酮
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,核磁 NMR, C谱, 氘代丙酮
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,核磁 NMR, C谱, 氘代丙酮
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,NMR,H谱,CDCl3
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,NMR,H谱,CDCl3
    Beniwal, Vijay; ChemPhysChem, (2015), 16(5), 1026-1034, CAplus
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,NMR,H谱
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,NMR,H谱,D2O
    Yang, Zhen-Zhen; Advanced Synthesis & Catalysis, (2010), 352(13), 2233-2240, CAplus
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,NMR,H谱
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,NMR,C谱,D2O
    Yang, Zhen-Zhen; Advanced Synthesis & Catalysis, (2010), 352(13), 2233-2240, CAplus
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,NMR,F谱
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,NMR,F谱
    Yang, Zhen-Zhen; Advanced Synthesis & Catalysis, (2010), 352(13), 2233-2240, CAplus
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,NMR,H谱,CD2Cl2
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,NMR,H谱,CD2Cl2
    Srour, Hassan; Green Chemistry, (2013), 15(5), 1341-1347, CAplus
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,NMR,C谱,CD2Cl2
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,NMR,C谱,CD2Cl2
    Srour, Hassan; Green Chemistry, (2013), 15(5), 1341-1347, CAplus
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,NMR,F谱,CD2Cl2
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,NMR,F谱,CD2Cl2
    Srour, Hassan; Green Chemistry, (2013), 15(5), 1341-1347, CAplus
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,NMR,B谱,CD2Cl2
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,NMR,B谱,CD2Cl2
    Srour, Hassan; Green Chemistry, (2013), 15(5), 1341-1347, CAplus
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,ESI-MS
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,ESI-MS
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,ESI-MS
    Yang, Zhen-Zhen; Advanced Synthesis & Catalysis, (2010), 352(13), 2233-2240, CAplus
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,ESI-MS
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,ESI-MS
    1-丁基-3-甲基咪唑四氟硼酸盐,1-butyl-3-methylimidazolium tetrafluoroborate,BMImBF4,174501-65,ESI-MS
    Srour, Hassan; Green Chemistry, (2013), 15(5), 1341-1347, CAplus

    1H NMR (400 MHz, D2O). δ 8.4469 (a, 1H); 7.3594 (b, 1H); 7.3081(c, 1H); 3.7128 (d, 3H); 4.0064 (e, 1H); 3.9887 (e, 1H); 3.9707 (e, 1H); 1.6181(f, 1H); 1.5998(f, 1H); 1.5814(f, 1H); 1.0754(g, 1H); 1.0571(g, 1H); 1.0385(g, 1H); 1.0200(g,1H); 0.6306(h, 1H); 0.6123(h, 1H); 0.5937(h, 1H). 来源：J. Phys. Chem. B 2012, 116, 7669−7675.

    FT-IR spectra. Wavenumbers a1:3162.47, a2:3121.73, a, b, c C-H; symmetric and antisymmetric stretching vibration; Wavenumbers b1:2964.74, b2:2877.45, d, e, f, g, h -CH3 –CH2, C-H symmetric and antisymmetric stretching vibration; Wavenumbers c1:1631.61, c2:1574.76, C=C, symmetric and antisymmetric stretching vibration; Wavenumbers d1:1468.25, d2:1431.93, C=N, symmetric and antisymmetric stretching vibration; Wavenumbers e1:1171.05, e2:1059.79, B-F, symmetric and antisymmetric stretching vibration. 来源：J. Phys. Chem. B 2012, 116, 7669−7675.

    BMImBF4电化学稳定性研究.jpg

    (a) CVs of [BMIm]BF4 on 2-mm-diameter Pt electrode, scan rate 50mVs-1; b-d, AC IV curve of [BMIm]BF4 on 2-mm-diameter Pt (b), Au (c), and GC (d) electrode with frequency of 20, 50, and 100 Hz, the auxiliary electrode: Pt wire. The AC current is root-mean-square.

    来源：Chemistry Letters Vol. 40 (2011) No. 12 P 1423-1425

    水溶液pH与浓度关系，来源：ChemSusChem 2010, 3, 1043 – 1047

  • 安全信息

    Code
    Hazard Statement
    Source
    H412
    Harmful to aquatic life with long lasting effects
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria
    H411
    Toxic to aquatic life with long lasting effects
    Boulder Scientific, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Isotec(now known as Sigma-aldrich), Merck Life Science (Sigma-Aldrich), Merck Life Science OY (Sigma-Aldrich)
    H401
    Toxic to aquatic life
    Boulder Scientific, Isotec(now known as Sigma-aldrich), Merck Life Science OY (Sigma-Aldrich)
    H335
    May cause respiratory irritation
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated
    H333
    May be harmful if inhaled
    Expert Curated
    H319
    Causes serious eye irritation
    Boulder Scientific, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Isotec(now known as Sigma-aldrich), Merck Life Science (Sigma-Aldrich), Merck Life Science OY (Sigma-Aldrich)
    H318
    Causes serious eye damage
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria
    H315
    Causes skin irritation
    Boulder Scientific, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Isotec(now known as Sigma-aldrich), Merck Life Science (Sigma-Aldrich), Merck Life Science OY (Sigma-Aldrich)
    H314
    Causes severe skin burns and eye damage
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria
    H302
    Harmful if swallowed
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated
    H301
    Toxic if swallowed
    Boulder Scientific, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Isotec(now known as Sigma-aldrich), Merck Life Science (Sigma-Aldrich), Merck Life Science OY (Sigma-Aldrich)

  • Other Names and Identifiers

    Canonical SMILES
    [F-][B+3]([F-])([F-])[F-].C1=C[N+](=CN1C)CCCC
    InChI
    InChI=1S/C8H15N2.BF4/c1-3-4-5-10-7-6-9(2)8-10;2-1(3,4)5/h6-8H,3-5H2,1-2H3;/q+1;-1
    InChI Key
    LSBXQLQATZTAPE-UHFFFAOYSA-N
    18 Other Names for this Substance
    • 1H-Imidazolium, 1-butyl-3-methyl-, tetrafluoroborate(1-) (9CI)
    • 1-Butyl-1-methylimidazolium tetrafluoroborate
    • 1-Butyl-3-methyl-1H-imidazol-3-ium tetrafloroborate
    • 1-Butyl-3-methyl-1H-imidazolium tetrafluoroborate
    • 1-Butyl-3-methyl-1H-imidazolium tetrafluoroborate(1-)
    • 1-Butyl-3-methyl-1H-imidazolium tetrafluoroborate(1-)
    • 1-Butyl-3-methylimidazolium tetrafluoroborate
    • 1-Butyl-3-methylimidazolium tetrafluoroborate(1-)
    • 1-Methyl-3-butylimidazolium tetrafluoroborate
    • 1-Methyl-3-butylimidazolium tetrafluoroborate(1-)
    • 1-n-Butyl-3-methylimidazolium tetrafluoroborate
    • 3-Butyl-1-methylimidazolium tetrafluoroborate
    • [1-Butyl-3-methylimidazolium]BF4
    • A 43205
    • Bmim tetrafluoroborate
    • BMIm tetrafluoroborate(1-)
    • BmimBF4
    • Butylmethylimidazolium tetrafluoroborate

  • 参考文献

    Experimental Properties

    Acoustic

    Biological

    Chemical

    Density

    Electrical

    Flow and Diffusion

    Interface

    Lipinski

    Mechanical

    Optical and Scattering

    Structure Related

    Thermal

    Experimental Spectra

    1H-NMR

    13C-NMR

    Additional Spectra

    hetero NMR

    IR

    Mass

    Raman

    UV and Visible

    X-Ray