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1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐

1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide

  • 分子式：C10H15F6N3O4S2
  • 分子量：419.36
  • CAS编号：174899-83-3
  • 纯度：99%

  • 基本信息

    产品名称： 1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐
    英文名称： 1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide
    CAS编号： 174899-83-3 简      写： BMImNTf2
    分 子 式 ： C10H15O4N3S2F6 分 子 量 ： 419.36
    纯      度： 99% 产品编号： CP0611

  • 物性数据

    项目 数据 测试条件 测试方法 数据来源
    long-term热稳定性  ℃ 227 2014客户文章
    表面张力  mN/m 32.5  25℃,101KPa  液体, Pendant drop shape  ILThermo
    纯度H2O  ppm <600     2013客户文章
    纯度H2O  ppm 248   323-343K真空干燥24h 2012客户文章
    电导率  mS/cm 20.17 80℃ H2O<200ppm(90℃,0.5kPa,10h) 2018客户文章
    电导率  mS/cm 18.31 75℃ H2O<200ppm(90℃,0.5kPa,10h) 2018客户文章
    电导率  mS/cm 16.51 70℃ H2O<200ppm(90℃,0.5kPa,10h) 2018客户文章
    电导率  mS/cm 14.77 65℃ H2O<200ppm(90℃,0.5kPa,10h) 2018客户文章
    电导率  mS/cm 13.11 60℃ H2O<200ppm(90℃,0.5kPa,10h) 2018客户文章
    电导率  mS/cm 11.58 55℃ H2O<200ppm(90℃,0.5kPa,10h) 2018客户文章
    电导率  mS/cm 10.15 50℃ H2O<200ppm(90℃,0.5kPa,10h) 2018客户文章
    电导率  mS/cm 8.77 45℃ H2O<200ppm(90℃,0.5kPa,10h) 2018客户文章
    电导率  mS/cm 7.52 40℃ H2O<200ppm(90℃,0.5kPa,10h) 2018客户文章
    电导率  mS/cm 6.37 35℃ H2O<200ppm(90℃,0.5kPa,10h) 2018客户文章
    电导率  mS/cm 5.32 30℃ H2O<200ppm(90℃,0.5kPa,10h) 2018客户文章
    电导率  mS/cm 4.33 25℃ H2O<200ppm(90℃,0.5kPa,10h) 2018客户文章
    电导率  mS/cm 4.03  25℃,101KPa  液体, Alternating current cell with electrodes  ILThermo
    电导率  mS/cm 3.47 20℃ H2O<200ppm(90℃,0.5kPa,10h) 2018客户文章
    电化学窗口  V 4.76     2014年整理
    密度  g/mL 1.4537 5℃ H2O<70ppm,卤素<100ppm 2015论文
    密度  g/mL 1.4457 15℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.4408 20℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.4368  25℃,101KPa  液体, Vibrating tube method  ILThermo
    密度  g/mL 1.436 25℃ 323-343K真空干燥24h 2012客户文章
    密度  g/mL 1.436 25℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.4342 25℃ H2O<70ppm,卤素<100ppm 2015论文
    密度  g/mL 1.4312 30℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.4264 35℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.4217 40℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.4169 45℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.4151 45℃ H2O<70ppm,卤素<100ppm 2015论文
    密度  g/mL 1.4122 50℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.4075 55℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.3963 65℃ H2O<70ppm,卤素<100ppm 2015论文
    热导率  W/(m.K) 0.128 293.00K   2014客户文章
    热分解onset温度  ℃ 434     2015客户文章
    热分解onset温度  ℃ 419     2014客户文章
    热分解peak温度  ℃ 453     2014客户文章
    热分解start温度  ℃ 336     2014客户文章
    熔点  ℃ -5    DSC/DTA  ILThermo
    粘度  cP 139.82 5℃ H2O<70ppm,卤素<100ppm 2015论文
    粘度  cP 78.02 15℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 61.32 20℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 51.6  25℃,101KPa  液体, Concentric cylinders viscometry  ILThermo
    粘度  cP 51.22 25℃ H2O<70ppm,卤素<100ppm 2015论文
    粘度  cP 48.93 25℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 39.84 30℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 32.91 35℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 27.56 40℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 24.36 45℃ H2O<70ppm,卤素<100ppm 2015论文
    粘度  cP 23.33 45℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 19.97 50℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 17.41 55℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 13.94 65℃ H2O<70ppm,卤素<100ppm 2015论文
    折光率   1.427     2012客户文章
    折光率   1.427  25℃,101KPa  液体, Standard Abbe refractometry  ILThermo

  • 参考谱图

    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,核磁 NMR, H谱, 氘代丙酮
    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,核磁 NMR, H谱, 氘代丙酮
    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,核磁 NMR, C谱, 氘代丙酮
    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,核磁 NMR, C谱, 氘代丙酮
    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,NMR,H谱,CDCl3
    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,NMR,H谱,CDCl3
    Beniwal, Vijay; ChemPhysChem, (2015), 16(5), 1026-1034, CAplus
    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,核磁 NMR, H谱, 氘代DMSO
    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,核磁 NMR, H谱, 氘代DMSO
    Rauber, Daniel; Journal of Molecular Liquids, (2016), 216, 246-258, CAplus
    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,核磁 NMR, F谱, 氘代DMSO
    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,核磁 NMR, F谱, 氘代DMSO
    Rauber, Daniel; Journal of Molecular Liquids, (2016), 216, 246-258, CAplus
    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,核磁 NMR, H谱, CD2Cl2
    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,核磁 NMR, H谱, CD2Cl2
    Srour, Hassan; Green Chemistry, (2013), 15(5), 1341-1347, CAplus
    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,核磁 NMR, C谱, CD2Cl2
    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,核磁 NMR, C谱, CD2Cl2
    Srour, Hassan; Green Chemistry, (2013), 15(5), 1341-1347, CAplus
    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,ESI-MS
    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,ESI-MS
    1-丁基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,BMImNTf2,174899-83-3,1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,ESI-MS
    Srour, Hassan; Green Chemistry, (2013), 15(5), 1341-1347, CAplus

  • 安全信息

    Code
    Hazard Statement
    Source
    H412
    Harmful to aquatic life with long lasting effects
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria
    H411
    Toxic to aquatic life with long lasting effects
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Merck Life Science OY (Sigma-Aldrich)
    H401
    Toxic to aquatic life
    Merck Life Science OY (Sigma-Aldrich)
    H373
    May cause damage to organs; through prolonged or repeated exposure
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Merck Life Science OY (Sigma-Aldrich)
    H333
    May be harmful if inhaled
    Expert Curated
    H319
    Causes serious eye irritation
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated
    H318
    Causes serious eye damage
    Merck Life Science OY (Sigma-Aldrich)
    H315
    Causes skin irritation
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated
    H314
    Causes severe skin burns and eye damage
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Merck Life Science OY (Sigma-Aldrich)
    H311
    Toxic in contact with skin
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated
    H301+H311
    Toxic if swallowed or in contact with skin
    Expert Curated, Merck Life Science OY (Sigma-Aldrich)
    H301
    Toxic if swallowed
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Merck

  • Other Names and Identifiers

    Canonical SMILES
    O=S(=O)([N-]S(=O)(=O)C(F)(F)F)C(F)(F)F.C1=C[N+](=CN1C)CCCC
    InChI
    InChI=1S/C8H15N2.C2F6NO4S2/c1-3-4-5-10-7-6-9(2)8-10;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h6-8H,3-5H2,1-2H3;/q+1;-1
    InChI Key
    INDFXCHYORWHLQ-UHFFFAOYSA-N
    38 Other Names for this Substance
    • 1H-Imidazolium, 1-butyl-3-methyl-, salt with 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamide (1:1) (9CI)
    • Methanesulfonamide, 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-, ion(1-), 1-butyl-3-methyl-1H-imidazolium (9CI)
    • 1-Butyl-3-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide
    • 1-Butyl-3-methyl-1H-imidazolium 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamide(1-)
    • 1-Butyl-3-methyl-1H-imidazolium N,N-bis(trifluoromethanesulfonyl)imide
    • 1-Butyl-3-methyl-1H-imidazolium N,N-bis[(trifluoromethyl)sulfonyl]amide
    • 1-Butyl-3-methyl-1H-imidazolium salt with 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamide
    • 1-Butyl-3-methyl-1H-imidazolium salt with 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamide (1:1)
    • 1-Butyl-3-methylimidazolium bis((trifluoromethy)sulfonyl)imide
    • 1-Butyl-3-methylimidazolium bis(trifluoromethane)sulfonimide
    • 1-Butyl-3-methylimidazolium bis(trifluoromethanesulfonimide) salt
    • 1-Butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide
    • 1-Butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imidate
    • 1-Butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide
    • 1-Butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide(1-)
    • 1-Butyl-3-methylimidazolium bis(trifluoromethanesylfonyl)imide(1-)
    • 1-Butyl-3-methylimidazolium bis(trifluoromethylsufonyl)imide
    • 1-Butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide
    • 1-Butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide(1-)
    • 1-Butyl-3-methylimidazolium bis(triflyl)imide
    • 1-Butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]amide
    • 1-Butyl-3-methylimidazolium bistriflamide
    • 1-Butyl-3-methylimidazolium bistriflimide
    • 1-Butyl-3-methylimidazolium N,N-bis(trifluoromethanesulfonyl)imide
    • 1-Butyl-3-methylimidazolium N,N-bis(trifluoromethylsulfonyl)amide
    • 1-Butyl-3-methylimidazolium triflimide
    • 1-Butyl-3-methylimidiazolium bis(trifluoromethanesulfonyl)imide
    • 1-Methyl-3-butylimidazolium bis(trifluoromethylsulfonyl)imide
    • 1-n-Butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide
    • 1-n-Butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide
    • 3-Butyl-1-methylimidazolium bis(trifluoromethanesulfonyl)imide
    • 3-Butyl-1-methylimidazolium bis(trifluoromethylsulfonyl)imide
    • [C4Mim+][Tf2N-]
    • BMI-N 111
    • BMI-TFSI
    • Bmim bis(trifluoromethanesulfonyl)imide
    • BMIM-TFSI
    • Butyl methyl imidazolium bis(trifluoromethyl)sulfonimide

  • 参考文献

    Experimental Properties

    Acoustic

    Biological

    Chemical

    Density

    Electrical

    Flow and Diffusion

    Interface

    Lipinski

    Mechanical

    Optical and Scattering

    Structure Related

    Thermal

    Experimental Spectra

    1H-NMR

    13C-NMR

    Additional Spectra

    hetero NMR

    IR

    Mass

    Raman

    UV and Visible

    X-Ray