四丁基溴化铵
Tetrabutyl-ammonium bromide
- 分子式：C16H36BrN
- 分子量：322.37
- CAS编号：1643-19-2
- 纯度：99%
基本信息
物性数据
参考谱图
安全信息
| Code |
Hazard Statement |
Source |
| H412 |
Harmful to aquatic life with long lasting effects |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Fisher Scientific, Merck Life Science OY (Sigma-Aldrich) |
| H411 |
Toxic to aquatic life with long lasting effects |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria |
| H402 |
Harmful to aquatic life |
Merck Life Science OY (Sigma-Aldrich) |
| H401 |
Toxic to aquatic life |
Expert Curated |
| H373 |
May cause damage to organs; through prolonged or repeated exposure |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria |
| H335 |
May cause respiratory irritation |
Acros Organics (Fisher Scientific), Acros Organics (a part of Thermo Fisher Scientific), Acros Organics (part of Thermo Fisher Scientific), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, J&K Scientific, New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals, Sigma-Aldrich (Merck), Strem Chemicals |
| H332 |
Harmful if inhaled |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals |
| H319 |
Causes serious eye irritation |
Acros Organics (Fisher Scientific), Acros Organics (a part of Thermo Fisher Scientific), Acros Organics (part of Thermo Fisher Scientific), Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Fisher Scientific, J&K Scientific, New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals, Sigma-Aldrich (Merck), Strem Chemicals |
| H318 |
Causes serious eye damage |
Expert Curated |
| H315+H320 |
Causes skin and eye irritation |
Merck Life Science OY (Sigma-Aldrich) |
| H315 |
Causes skin irritation |
Acros Organics (Fisher Scientific), Acros Organics (a part of Thermo Fisher Scientific), Acros Organics (part of Thermo Fisher Scientific), Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Fisher Scientific, J&K Scientific, New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals, Sigma-Aldrich (Merck), Strem Chemicals |
| H312 |
Harmful in contact with skin |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria |
| H302 |
Harmful if swallowed |
Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Fisher Scientific, Merck Life Science OY (Sigma-Aldrich), New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals |
Other Names and Identifiers
Canonical SMILES
[Br-].CCCC[N+](CCCC)(CCCC)CCCC
InChI
InChI=1S/C16H36N.BrH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
InChI Key
JRMUNVKIHCOMHV-UHFFFAOYSA-M
13 Other Names for this Substance
- 1-Butanaminium, N,N,N-tributyl-, bromide (9CI)
- Ammonium, tetrabutyl-, bromide (8CI)
- Tetrabutylammonium bromide (6CI, 7CI)
- 28296B
- 28296F
- Actiron 43-65
- Aliquat 100
- AP 6G
- Mastermix MB 4988
- TBAB
- TBAB 50A
- TBABr
- Tetra-n-butylammonium bromide
参考文献
Experimental Properties
Chemical
- (1) Albeniz, Ana C.; Journal of Polymer Science, Part A: Polymer Chemistry, (2006), 44(19), 5682-5691, CAplus
- (2) Pradines, Vincent; Journal of Physical Organic Chemistry, (2006), 19(6), 350-358, CAplus
- (3) Wang, Ten-Tsai; Journal of the Chinese Institute of Chemical Engineers, (2003), 34(2), 187-199, CAplus
Electrical
Flow and Diffusion
Mechanical
Nuclear
Thermal
- (1) McMichael, Kirk D.; Journal of Organic Chemistry, (1961), 26, 620-1, CAplus
- (2) Calo, Vincenzo; Organometallics, (2004), 23(22), 5154-5158, CAplus
- (3) Lapidus, Albert; Journal of Molecular Catalysis A: Chemical, (2006), 252(1-2), 245-251, CAplus
- (4) Shim, Jae-Jin; Bulletin of the Korean Chemical Society, (2006), 27(5), 744-746, CAplus
- (5) Ranu, Brindaban C.; Australian Journal of Chemistry, (2004), 57(6), 605-608, CAplus
- (6) Balazs, Attila; Journal of Molecular Catalysis A: Chemical, (2006), 244(1-2), 105-109, CAplus
- (7) Kustov, A. V.; Russian Journal of Physical Chemistry, (2006), 80(1), 56-62, CAplus
- (8) Blanco, L. H.; Journal of Thermal Analysis and Calorimetry, (2008), 92(3), 683-686, CAplus
- (9) Prathibha, B. S.; Research Journal of Recent Sciences, (2013), 2(4), 1-10, CAplus
- (10) Dyadin, Yu. A.; Doklady Akademii Nauk SSSR, (1972), 203(5), 1068-71 [Chem], CAplus
- (11) Finkelstein, Manuel; Journal of Organic Chemistry, (1986), 51(18), 3548-51, CAplus
- (12) Ye, Lina; Chemistry of Materials, (2007), 19(25), 6331-6337, CAplus
Experimental Spectra
1H-NMR
- (1) Spectral data were obtained from Enamine Ltd.
- (2) Denmark, Scott E.; Journal of the American Chemical Society, (2012), 134(32), 13415-13429, CAplus
- (3) "Integrated Spectral Data Base System of Organic Compounds" data were obtained from the National Institute of Advanced Industrial Science and Technology (Japan)
- (4) Hanawalt, Erin M.; Organometallics, (2004), 23(3), 416-422, CAplus
- (5) Fung, B. M.; Journal of Magnetic Resonance, (2004), 169(2), 351-359, CAplus
- (6) Park, Sungwon; Environmental Science & Technology, (2013), 47(13), 7571-7577, CAplus
- (7) Bernard, Franciele L.; Energy & Fuels, (2017), 31(9), 9840-9849, CAplus
13C-NMR
- (1) Wolfgang Robien / University of Vienna (Spectral Data were obtained from John Wiley & Sons, Inc.)
- (2) Copyright Bio-Rad Laboratories. All Rights Reserved.
- (3) Hanawalt, Erin M.; Organometallics, (2004), 23(3), 416-422, CAplus
hetero NMR
IR
- (1) Spectral data were obtained from John Wiley & Sons, Inc.
- (2) Sigma-Aldrich Co. LLC. (Spectral Data were obtained from John Wiley & Sons, Inc.)
- (3) Copyright Bio-Rad Laboratories. All Rights Reserved.
- (4) "Integrated Spectral Data Base System of Organic Compounds" data were obtained from the National Institute of Advanced Industrial Science and Technology (Japan)
- (5) Burnett, Andrew D.; Analytical Chemistry (Washington, DC, United States), (2013), 85(16), 7926-7934, CAplus
- (6) Bernard, Franciele L.; Energy & Fuels, (2017), 31(9), 9840-9849, CAplus
- (7) Ye, Lina; Chemistry of Materials, (2007), 19(25), 6331-6337, CAplus
- (8) Rao, A. Venkateswara; Journal of the Electrochemical Society, (1987), 134(11), 2777-83, CAplus
Mass
- (1) Spectral data were obtained from John Wiley & Sons, Inc.
- (2) "Integrated Spectral Data Base System of Organic Compounds" data were obtained from the National Institute of Advanced Industrial Science and Technology (Japan)
- (3) Gouw, Joost W.; Rapid Communications in Mass Spectrometry, (2002), 16(10), 905-912, CAplus
- (4) Kavallieratos, Konstantinos; Journal of the American Society for Mass Spectrometry, (2005), 16(8), 1377-1383, CAplus
- (5) Neue, Uwe D.; Journal of Separation Science, (2007), 30(7), 949-963, CAplus
Raman
- (1) Sigma-Aldrich Co. LLC. (Spectral Data were obtained from John Wiley & Sons, Inc.)
- (2) Davis, Joel G.; Journal of Physical Chemistry B, (2015), 119(29), 9417-9422, CAplus
